Pressure dependence of diffusion coefficient and orientational relaxation time for acetonitrile and methanol in water: DRISM/mode-coupling study

We present results of theoretical description and numerical calculation of the dynamics of molecular liquids based on the Reference Interaction Site Model / Mode-Coupling Theory. They include the temperature-pressure(density) dependence of the translational diffusion coefficients and orientational relaxation times for acetonitrile and methanol in water at infinite dilution. Anomalous behavior, i.e. the increase in mobility with density, is observed for the orientational relaxation time of methanol, while acetonitrile does not show any deviations from the usual. This effect is in qualitative agreement with the recent data of MD simulation and with experimental measurements, which tells us that presented theory is a good candidate to explain such kind of anomalies from the microscopical point of view and with the connection to the structure of the molecules.Comment: 10 pages, 2 eps-figures, 3 table

Superconductivity in S-substituted FeTe

We have successfully synthesized a new superconducting phase of FeTe1-xSx with a PbO-type structure. It has the simplest crystal structure in iron-based superconductors. Superconducting transition temperature is about 10 K at x = 0.2. The upper critical field Hc2 was estimated to be ~70 T. The coherent length was calculated to be ~2.2 nm. Because FeTe1-xSx is composed of nontoxic elements, this material is a candidate for applications and will activate more and more research on iron-based superconductor.Comment: 13 pages, 10 figure

Stability criteria of the Vlasov equation and quasi-stationary states of the HMF model

We perform a detailed study of the relaxation towards equilibrium in the Hamiltonian Mean-Field (HMF) model, a prototype for long-range interactions in $N$-particle dynamics. In particular, we point out the role played by the infinity of stationary states of the associated $N ~$ Vlasov dynamics. In this context, we derive a new general criterion for the stability of any spatially homogeneous distribution, and compare its analytical predictions with numerical simulations of the Hamiltonian, finite $N$, dynamics. We then propose and verify numerically a scenario for the relaxation process, relying on the Vlasov equation. When starting from a non stationary or a Vlasov unstable stationary initial state, the system shows initially a rapid convergence towards a stable stationary state of the Vlasov equation via non stationary states: we characterize numerically this dynamical instability in the finite $N$ system by introducing appropriate indicators. This first step of the evolution towards Boltzmann-Gibbs equilibrium is followed by a slow quasi-stationary process, that proceeds through different stable stationary states of the Vlasov equation. If the finite $N$ system is initialized in a Vlasov stable homogenous state, it remains trapped in a quasi-stationary state for times that increase with the nontrivial power law $N^{1.7}$. Single particle momentum distributions in such a quasi-stationary regime do not have power-law tails, and hence cannot be fitted by the $q$-exponential distributions derived from Tsallis statistics.Comment: To appear in Physica

Inflation by non-minimal coupling

Inflationary scenarios based on simple non-minimal coupling and its generalizations are studied. Generalizing the form of non-minimal coupling to "K(phi)R" with an arbitrary function K(phi), we show that the flat potential still is obtainable when V(phi)/K^2(phi) is asymptotically constant. Very interestingly, if the ratio of the dimensionless self-coupling constant of the inflaton field and the non-minimal coupling constant is small the cosmological observables for general monomial cases are in good agreement with recent observational data.Comment: 9 pages, 1 figur

Modulation Mechanism of TeV, GeV, and X-ray Emission in LS5039

The emission mechanism of the gamma-ray binary LS5039 in energy bands of TeV, GeV, and X-ray is investigated. Observed light curves in LS5039 show that TeV and GeV fluxes anticorrelate and TeV and X-ray fluxes correlate. However, such correlated variations have not been explained yet reasonably at this stage. Assuming that relativistic electrons are injected constantly at the location of the compact object as a point source, and that they lose energy only by the inverse Compton (IC) process, we calculate gamma-ray spectra and light curves by the Monte Carlo method, including the full electromagnetic cascade process. Moreover, we calculated X-ray spectra and light curves by using the resultant electron distribution. As a result, we are able to reproduce qualitatively spectra and light curves observed by HESS, Fermi, and Suzaku for the inclination angle i = 30 dig and the index of injected electron distribution p = 2.5. We conclude that TeV-GeV anticorrelation is due to anisotropic IC scattering and anisotropic gamma-gamma absorption, and that TeV-X correlation is due to the dependence of IC cooling time on orbital phases. In addition, the constraint on the inclination angle implies that the compact object in LS5039 is a black hole.Comment: 27 pages, 7 figures, published in The Astrophysical Journa

Photon Mass Bound Destroyed by Vortices

The Particle Data Group gives an upper bound on the photon mass $m < 2 \times 10^{-16}$eV from a laboratory experiment and lists, but does not adopt, an astronomical bound $m < 3 \times 10^{-27}$eV, both of which are based on the plausible assumption of large galactic vector-potential. We argue that the interpretations of these experiments should be changed, which alters significantly the bounds on $m$. If $m$ arises from a Higgs effect, both limits are invalid because the Proca vector-potential of the galactic magnetic field may be neutralized by vortices giving a large-scale magnetic field that is effectively Maxwellian. In this regime, experiments sensitive to the Proca potential do not yield a useful bound on $m$. As a by-product, the non-zero photon mass from Higgs effect predicts generation of a primordial magnetic field in the early universe. If, on the other hand, the galactic magnetic field is in the Proca regime, the very existence of the observed large-scale magnetic field gives $m^{-1}\gtrsim 1$kpc, or $m\lesssim 10^{-26}$eV.Comment: 9 pages, discussion of primordial magnetic field adde

Site-site memory equation approach in study of density/pressure dependence of translational diffusion coefficient and rotational relaxation time of polar molecular solutions: acetonitrile in water, methanol in water, and methanol in acetonitrile

We present results of theoretical study and numerical calculation of the dynamics of molecular liquids based on combination of the memory equation formalism and the reference interaction site model - RISM. Memory equations for the site-site intermediate scattering functions are studied in the mode-coupling approximation for the first order memory kernels, while equilibrium properties such as site-site static structure factors are deduced from RISM. The results include the temperature-density(pressure) dependence of translational diffusion coefficients D and orientational relaxation times t for acetonitrile in water, methanol in water and methanol in acetonitrile, all in the limit of infinite dilution. Calculations are performed over the range of temperatures and densities employing the SPC/E model for water and optimized site-site potentials for acetonitrile and methanol. The theory is able to reproduce qualitatively all main features of temperature and density dependences of D and t observed in real and computer experiments. In particular, anomalous behavior, i.e. the increase in mobility with density, is observed for D and t of methanol in water, while acetonitrile in water and methanol in acetonitrile do not show deviations from the ordinary behavior. The variety exhibited by the different solute-solvent systems in the density dependence of the mobility is interpreted in terms of the two competing origins of friction, which interplay with each other as density increases: the collisional and dielectric frictions which, respectively, increase and decrease with increasing density.Comment: 13 pages, 8 eps-figures, 3 tables, RevTeX4-forma